1-(2-Phenylbenzyl)-3-(2,4,6-trimethylbenzyl)imidazolidinium bromide
Document Type
Article
Publication Date
12-1-2008
Abstract
In the title salt, C26H29N2+·Br-, which may serve as a precursor for N-heterocyclic carbenes, the imidazolidine ring adopts a twist conformation with a pseudo-twofold axis passing through the N - C - N carbon and the opposite C - C bond. The N - C - N bond angle [113.0 (4)°] and C - N bond lengths [1.313 (6) and 1.305 (6) Å] confirm the existence of strong resonance in this part of the mol-ecule. In the crystal, a C - H?Br inter-action is present. The dihedral angle between the biphenyl rings is 64.3 (2)° and the phenyl rings make angles of 76.6 (3) and 18.5 (3)° with the plane of the imidazolidine ring.
Recommended Citation
Arslan, Hakan; VanDerveer, Don; Ya?ar, Sedat; Özdemir, Smail; and Çetinkaya, Bekir, "1-(2-Phenylbenzyl)-3-(2,4,6-trimethylbenzyl)imidazolidinium bromide" (2008). College of Health, Science, and Technology. 18.
https://digitalcommons.uncfsu.edu/college_health_science_technology/18