1,3-Bis(4-tert-butyl-benz-yl)-4,5-dihydro-imidazolium chloride monohydrate

Document Type

Article

Publication Date

2-23-2009

Abstract

In the title compound, C25H35N2 +·Cl -·H2O, the imidazolidine ring adopts a twisted conformation, with a pseudo-twofold axis passing through the N - C - N carbon and the opposite C - C bond. The N - C - N fragment of the imidazolidine ring shows some degree of both double- and single-bond character due to partial electron delocalization. One of the tert-butyl groups is disordered over two conformations with occupancies of 0.714 (8) and 0.286 (8). In the crystal, O - H?Cl and C - H?O hydrogen bonds help to establish the packing.

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